Conversion of Marine Structures to Calcium Phosphate Materials: Mechanisms of Conversion using two Different Phosphate Solutions

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dc.contributor.authorMacha, Innocent J
dc.contributor.authorGrossin, David
dc.contributor.authorBen-Nissan, Besim
dc.date.accessioned2016-06-21T07:12:14Z
dc.date.available2016-06-21T07:12:14Z
dc.date.issued2016-03
dc.descriptionFull text can be accessed at http://www.scientific.net/KEM.696.36en_US
dc.description.abstractMarine structure, coralline materials were converted to calcium phosphate using two different phosphate solutions. The aim was to study the conversion mechanisms under acidic and basic environment at moderate conditions of temperature. Crystal growth and morphology of converted corals were characterized by XRD and SEM respectively. The results suggested that under acidic conditions (H<sub>3</sub>PO<sub>4</sub>), dissolution and precipitation control and direct the crystal formation and morphology in which transition from plate like to rod like hydroxyapatite structure was favoured. Metastable phase such as monetite formed and transformed to HAp during reaction. During the first hour of the dissolution a monetite and hydroxyapatite mixture precipitates and then the full conversion to hydroxyapatite is observed. On the other hand, under basic conditions (NH<sub>4</sub>)2HPO<sub>4</sub>, just diffusional surface conversion of the calcium carbonate structure of coralline materials to hydroxyapatite and a very small amount of tri-calcium phosphate is observed. The mechanism can be classified as the solid-state topotactic ion-exchange reaction mechanism.
dc.identifier.citationMacha, I.J., Grossin, D. and Ben-Nissan, B., 2016. Conversion of marine structures to calcium phosphate materials: Mechanisms of conversion using two different phosphate solutions. In Key Engineering Materials (Vol. 696, pp. 36-39). Trans Tech Publications.en_US
dc.identifier.doi10.4028/www.scientific.net/KEM.696.36
dc.identifier.urihttp://hdl.handle.net/20.500.11810/2634
dc.language.isoenen_US
dc.subjectConversionen_US
dc.subjectCoralline Topotacticen_US
dc.subjectIon-Exchangeen_US
dc.subjectMarine Structureen_US
dc.subjectPhosphateen_US
dc.subjectSolid Stateen_US
dc.titleConversion of Marine Structures to Calcium Phosphate Materials: Mechanisms of Conversion using two Different Phosphate Solutionsen_US
dc.typeJournal Articleen_US
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