A novel blue-emitting phosphors (CsBaYB6O12:Ce3+): Potential applications in w-LEDs and X-ray phosphors

dc.contributor.authorNtarisa, Amos Vincent
dc.contributor.authorD Joseph, Daniel
dc.contributor.authorD, Balaji
dc.contributor.authorRaja, Arumugam
dc.contributor.authorKim, HongJoo
dc.contributor.authorNguyen, Duy Quang
dc.date.accessioned2022-10-18T10:10:55Z
dc.date.available2022-10-18T10:10:55Z
dc.date.issued2021-08-25
dc.description.abstractWe have synthesized powder samples of pure and Ce3+ doped cesium barium yttrium hexaborate (CsBaYB6O12) using a standard solid-state reaction technique. The prepared samples were characterized by different techniques. Powder X-ray diffraction (PXRD) was used to identify the phase purity of the prepared phosphors. The field emission scanning electron microscopy (FE-SEM) technique was used to examine the size and shape of the synthesized powder samples. The energy-dispersive spectral analysis (EDS) was used to identify the elements present in the synthesized compounds. X-ray-induced luminescence spectra, photoluminescence (PL), and thermoluminescence (TL) analysis were used to investigate the luminescence properties of the prepared compound. The rare earth ion of Ce3+ improves the intrinsic luminescence of CsBaYB6O12 and 4 mol% was found to be the optimal concentration. The dopants found to have two different excitation PL bands at 340 nm and 360 nm which yields the same emission bands of 385 and 417 nm which are well-matched with that found in the X-ray emission bands. The kinetic parameters of the measured experimental TL glow curve has been studied by various standard methods such as deconvolution, Variable heating rate and initial rise method. In this manuscript we report the luminescence properties of the prepared phosphors in a detailed manner for the first time.en_US
dc.description.sponsorshipThis research was supported by the National Research Foundation of Korea (NRF No-2018R1A6A1A06024970 and No-2019R1I1A1A01052459) funded by the Ministry of Education, Korea. One of the authors Dr. D.Balaji acknowledged the DST-FIST, Government of India, New Delhi for generously providing the Research Instruments Facility (Grant No. SR/FST/College-2017/140 (C), dt. 1 4.08.2018).en_US
dc.identifier.issn0925-8388
dc.identifier.urihttp://hdl.handle.net/20.500.11810/5889
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.subjectBorate, Phosphors. Solid-state reaction, Luminescenceen_US
dc.titleA novel blue-emitting phosphors (CsBaYB6O12:Ce3+): Potential applications in w-LEDs and X-ray phosphorsen_US
dc.typeJournal Article, Peer Revieweden_US
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