Alkyl Group-Tagged Ruthenium Indenylidene Complexes: Synthesis, Characterization and Metathesis Activity

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dc.contributor.authorYu, Baoyi
dc.contributor.authorHamad, Fatma B.
dc.contributor.authorLeus, Karen
dc.contributor.authorLyapkov, Alex A.
dc.contributor.authorVan Hecke, Kristof
dc.contributor.authorVerpoort, Francis
dc.date.accessioned2016-06-18T18:13:19Z
dc.date.available2016-06-18T18:13:19Z
dc.date.issued2015
dc.description.abstractWe report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)2inwhich R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidenecatalysts were analyzed by means of IR, elementa l analysis, NMR and single crystal X-Ray diffractionanalysis. Furthermore, the catalytic performance of these new complexes was examined in dif ferentmetathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activ-ity in comparison with the commercially available catalyst 3aen_US
dc.identifier.citationYu, B., Hamad, F.B., Leus, K., Lyapkov, A.A., Van Hecke, K. and Verpoort, F., 2015. Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity. Journal of Organometallic Chemistry, 791, pp.148-154.en_US
dc.identifier.doi10.1002/chin.201551058
dc.identifier.urihttp://hdl.handle.net/20.500.11810/2577
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.subjectOlefin metathesisen_US
dc.subjectRutheniumen_US
dc.subjectIndenylideneen_US
dc.subjectHomogeneousen_US
dc.subjectCatalysisen_US
dc.titleAlkyl Group-Tagged Ruthenium Indenylidene Complexes: Synthesis, Characterization and Metathesis Activityen_US
dc.typeJournal Article, Peer Revieweden_US
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