Bidentate Schiff Base Ruthenium Complexes as Precursors of Homogeneous and Immobilized Catalysts

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dc.contributor.authorVerpoort, Francis
dc.contributor.authorYu, Baoyi
dc.contributor.authorHamad, Fatma B.
dc.contributor.authorVelazquez, Heriberto D.
dc.contributor.authorLuo, Zhixiong
dc.date.accessioned2016-06-18T18:15:05Z
dc.date.available2016-06-18T18:15:05Z
dc.date.issued2013
dc.descriptionFull text can be accessed at http://hdl.handle.net/1854/LU-4119567en_US
dc.description.abstractThe paper presents an overview of the work conducted in our group on the synthesis of a novel class of homogeneous and immobilized Ru-complexes containing Schiff bases as O, N-bidentate ligands benefiting from a versatile, quite general and thoroughly exemplified two-step procedure. The new Ru-complexes with improved stability incorporate a variety of Schiff bases, associated with traditional inorganic and organic ligands such as chloride, phosphanes, arenes, cyclodienes, NHC etc., and different carbenes (alkylidene, vinylidene, allenylidene and indenylidene). By a proper choice of the Schiff base, useful physical and chemical properties of the derived Ru-complexes could be induced resulting in tunable catalytic activity for metathesis and related processes. A pertinent example is the latency of selected Schiff base Ru catalysts which by becoming active only under specific conditions (heat or acid activation) are ideal for industrial applications, e.g. reaction injection molding processes. The synthetic approaches that are critically discussed in this chapter have led to a diversity of Ru-complexes of which several members have risen to the rank of commercial catalysts.en_US
dc.identifier.citationVerpoort, F., Yu, B., Hamad, F.B. and Diaz, H., 2013. Bidentate Schiff Base Ruthenium Complexes as Precursors of Homogeneous and Immobilized Catalysts. Advances in Organic Synthesis, 3, p.3.en_US
dc.identifier.doi10.2174/9781608054688113030003
dc.identifier.isbn9781608055876
dc.identifier.urihttp://hdl.handle.net/20.500.11810/2582
dc.language.isoenen_US
dc.publisherBentham Scienceen_US
dc.subjectIsomerizationen_US
dc.subjectVinyl ester synthesisen_US
dc.subjectAtom transfer radical polymerizationen_US
dc.subjectKharash additionen_US
dc.subjectCross metathesisen_US
dc.subjectLatent catalysten_US
dc.subjectRing opening metathesisen_US
dc.subjectRing closing metathesisen_US
dc.subjectOlefin Metathesisen_US
dc.subjectHeterogeneous catalysisen_US
dc.subjectSchiff base ligandsen_US
dc.subjecthomogeneous catalysisen_US
dc.subjectruthenium hydridesen_US
dc.subjectRuthenium arenesen_US
dc.subjectRuthenium indenylidenesen_US
dc.subjectRuthenium vinylidenesen_US
dc.subjectRuthenium allenylidenesen_US
dc.subjectRuthenium carbenesen_US
dc.subjectOrganometallic chemistryen_US
dc.subjectRutheniumen_US
dc.titleBidentate Schiff Base Ruthenium Complexes as Precursors of Homogeneous and Immobilized Catalystsen_US
dc.typeBook chapteren_US
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