Synthesis and Reactions of Some Derivatives Of (3,6 S,9 R,10 R,11 S)-1,4,7-Trioxaspiro[5,5]Undecane-3,9,10,11-Tetrol: Novel Quasi-Saccharides 1 Presented at the 2nd International Meeting of the Portuguese Carbohydrate Chemistry Group, Porto, Portugal, 21–25 September 1997. 1

Regeling, Henk; Sunghwa, Fortunatus; Zwanenburg, Binne; de Gelder, Rene; Chittenden, Gordon J. F.

Synthesis and Reactions of Some Derivatives Of (3,6 S,9 R,10 R,11 S)-1,4,7-Trioxaspiro[5,5]Undecane-3,9,10,11-Tetrol: Novel Quasi-Saccharides 1 Presented at the 2nd International Meeting of the Portuguese Carbohydrate Chemistry Group, Porto, Portugal, 21–25 September 1997. 1

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Synthesis and reactions of some derivatives of (3,6S,9R,10R,11S)-1,4,7-trioxaspiro[5,5]undecane-3,9,10,11-tetrol novel quasi-saccharides.pdf (46.07 KB)

Date

1998-10

Authors

Chittenden, Gordon J. F.

Abstract

The title compound was obtained by reductive ozonolysis of allyl β-d-fructopyranoside. The synthesis and characterization of a number of C-3-substituted derivatives using conventional carbohydrate procedures is described. Some of the products may be of biological interest as carbohydrate mimics. The structures of two of the basic products (8 and 9) were substantiated by X-ray diffraction studies. Do you want to read the rest of this article?Access full-text

Description

Full text can be accessed at http://www.sciencedirect.com/science/article/pii/S0144861798000782

Keywords

Spiro-fructosides-quasisaccharides, Carbohydrates mimics, X-ray diffraction

Citation

Regeling, H., Sunghwa, F., Zwanenburg, B., de Gelder, R. and Chittenden, G.J., 1998. Synthesis and reactions of some derivatives of (3, 6S, 9R, 10R, 11S)-1, 4, 7-trioxaspiro [5, 5] undecane-3, 9, 10, 11-tetrol: novel quasi-saccharides. Carbohydrate polymers, 37(3), pp.323-333.

URI

http://hdl.handle.net/20.500.11810/3372

Collections

Chemistry Department

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