Browsing by Author "Ikingura, Justinian R."
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Item Application of Infra-Red Spectral and Multi-Element Analyses in the Gold Exploration in North Mara Mines, Tanzania(2008) Kazimoto, Emmanuel O.; Ikingura, Justinian R.; Halley, S.A combination of Short Wavelength Infra red (SWIR) spectral and multielement analyses was used to characterize certain hydrothermal alteration, pathfinder elements and their distribution within gold deposits in the Archean Musoma- Mara greenstone belt in Tanzania. The aim was to fingerprint hydrothermal systems responsible for the formation of major gold deposits in the belt. The SWIR spectra of white mica and chlorite from the samples revealed compositional zoning which reflects pH changes associated with hydrothermal fluid- rock interaction during mineralization. White mica crystallinity is variable in the deposits reflecting thermal gradient during hydrothermal alteration. On the other hand, gold pathfinder elements distribution showed extension of pathfinder element signature beyond a distance of 600 m width from the ore zone with either As and Sb association or Ag and Bi association. This suggests that different redox conditions have affected the deposits. This study confirms that a combination of SWIR spectral and multielement data is a cost-effective method in generating mineralization targets and can be applicable in areas with similar styles of mineralization.Item Characterization of Hydrothermal Alteration Mineralogy and Pathfinder Elements in the Exploration for gold in North Mara mines,Tanzania(2015) Kazimoto, Emmanuel O.; Ikingura, Justinian R.; Halley, ScottA combination of mineralogical and multielement analyses was used to characterize the hydrothermal alteration,pathfinder elements and their distribution within the gold deposits in North Mara mines,the Archean Musoma-Mara greenstone belt,Tanzania. The aim was to evaluate the suitability of alteration mineral assemblages and composition as an effective exploration marker for fingerprinting hydrothermalItem Environmental Assessment of Mercury Dispersion, Transformation and Bioavailability in the Lake Victoria Goldfields, Tanzania(Elsevier, 2006) Ikingura, Justinian R.; Akagi, Hirokatsu; Mujumba, Jean; Messo, CharlesEnvironmental dispersion and transformation of mercury discharged from gold mining operations has been investigated in field and laboratory studies in order to provide better understanding of the degree of mercury (Hg) pollution and bioavailability in the Lake Victoria goldfields (LVGF) ecosystems. This paper reviews results already published elsewhere and presents additional data on Hg dynamics in the LVGF. Studies conducted at the Mugusu and Rwamagaza artisanal mines indicated different degrees of Hg contamination and dispersion in environmental matrices. Mercury concentration in contaminated river sediments near the Mugusu mine varied from 6.0 to 0.5 mg/kg on a dry weight basis. The highest Hg contamination levels (165-232 mg/kg) were associated with mine tailings at the Rwamagaza mine. Mercury concentrations in fish representing different dietary habits on the southwestern shore of Lake Victoria at the Nungwe Bay were very low (2-35 microg/kg) and thought to represent background levels. These and other results suggested that the use of Hg in gold extraction in the LVGF has not caused high Hg levels in lake fish. The study of Hg in lichens showed Parmelia lichen to be an effective bioindicator for atmospheric Hg contamination due to Hg emissions from gold-amalgam firing and purification operations. The Hg levels in the lichens around the Mugusu mine ranged from 3.1 to 0.1 microg/g; the highest levels were recorded in the lichens sampled close to gold-amalgam processing sites. The regional background level in the Parmelia lichen was 0.05-0.10 microg/g, with a mean level of 0.07 microg/g. Studies of Hg transformation in the mine tailings revealed unexpectedly high methylmercury (MeHg) levels in the tailings (629-710 ng/g), which indicated that oxidation and methylation of metallic Hg in the tailings occurred at significant levels under tropical conditions. Re-equilibration of the tailings with freshwater (FW) indicated the MeHg was firmly bound in the tailings and therefore very little MeHg was released to the water column (0.2-1.5 ng/L). The methylation of Hg in tropical loamy clay soil contaminated with HgCl(2) (5 mg Hg/kg) yielded MeHg concentrations of 11 and 14 ng/g when inundated with seawater and FW, respectively, for 4 weeks. Little MeHg was transferred from the soil to the equilibrated water (< or = 0.4 ng/L). Atmospheric exposure of the soil pre-inundated with FW resulted in net degradation of MeHg during the 1st week of exposure, followed by net production and accumulation of MeHg in the soil (up to 15.5 ng/g) during atmospheric desiccation. Mercury uptake by fish from the Hg(0)-contaminated aquatic sediment-tailings system in the aquarium experiment was found to be low, suggesting the low availability of MeHg for bioaccumulation in the system. These and other results provide useful insights into Hg transformation, mobility and bioavailability in tropical aquatic systems affected by Hg pollution from gold mining operations.Item Geology and Geochemistry of Bauxite Deposits in Lushoto District, Usambara Mountains, Tanzania(Elsevier, 2003) Mutakyahwa, M. K. D.; Ikingura, Justinian R.; Mruma, Abdulkarim H.Bauxite deposits in the Usambara Mountains of north eastern Tanzania occur as remnants of residual deposits on two geomorphologically related plateaus of Mabughai-Mlomboza and Kidundai at Magamba in Lushoto, Usambara Mountains. The parent rocks for the deposits are mainly granulites and feldspathic gneisses of Neoproterozoic Mozambique belt. The plateaus represent a preserved Late Cretaceous–Lower Tertiary old land surface (African surface). Other parts of the Usambara Mountains and the neighbouring Pare Mountains are covered mostly by red–brown lateritic soils and impure reddish-brown kaolinitic clays. The bauxite deposits contain mainly Al2O3 (40–69 wt.%), Fe2O3 (3–10 wt.%), SiO2 (0.16–7 wt.%) and other elements occur in quantities not substantial to affect the quality or processing of the bauxite, and are attributed to the presence of relic minerals. Gibbsite makes up to 98 vol.% of the bauxite ore in special cases. Gibbsite is accompanied by goethite in the ore. Boehmite occurs in small amounts and is usually accompanied by hematite. Impurities include goethite, hematite, kaolinite, and minor relic quartz and microcline. Kaolinite is the sole clay mineral encountered in the bauxite ore, suggesting mature soil profiles and a development of the bauxite deposits on a well-drained peneplanation. Ore reserve estimates from the drilling data and surface geological mapping of the deposits yielded bauxite reserves of about 37 million tonnes.Item Lichens as a Good Bioindicator of Air Pollution by Mercury in Small-Scale Gold Mining Areas, Tanzania(Springer Link, 2002) Ikingura, Justinian R.; Akagi, HirokatsuItem Mercury and Mining in Africa with Special Reference to Tanzania(1997) Ikingura, Justinian R.; Mutakyahwa, M. K. D.; Kahatano, J .M. J.A study of gold (Au) mining areas in Tanzania is being undertaken to assess environmental impacts arising from the use of mercury (Hg) in gold extraction. Initial results already indicated the presence of elevated Hg concentrations in environmental samples from the mining areas. The mean Hg concentration in river sediments in 4.19 µg/l. soils within gold mining and processing centres exhibit high Hg content (mean 3.39 µg/g) that decreases rapidly to background regional values within a distance of a few kilometres. A review of published Hg data for sediments, fish and aquatic plants from African inland and coastal waters revealed, with a few exceptions, low Hg concentrations close to natural background levels.Item Methyl Mercury Production and Distribution in River Water-Sediment Systems Investigated Through Radiochemical Techniques(Springer Link, 2000) Guimarães, Jean R. D.; Ikingura, Justinian R.; Akagi, HirokatsuThe toxicological consequences of Hg releases to the environment are largely governed by the conversion ofinorganic Hg to the most toxic methylmercury (MeHg), that is biomagnified through aquatic food chains. To gain further insight on the biological and physico-chemical factors controlling MeHg production and distribution among freshwater sediments and water, we used a sensitive and specific radiochemical procedure, developed at the National Institute for Minamata Disease. Systems containing 203Hg2+-spiked sediment cores (0.7 g total Hg g-1 d.w.) and overlying water, both from a pristine mountain stream in Southern Japan, were incubated for 21–38 days in different conditions. Inorganic Hg and MeHg in sediment and water were extracted in dithizone-benzene and measured after separation by thin-layer chromatography. The conversion of added Hg to MeHg was 3.0 to 13.7% in sediments, with a tendency for higher proportions in the top layers. Surprisingly, more MeHg was found in the sediment (11.3%) and water (66.5%) of a system bubbled with air than in one bubbled with nitrogen (4.2 and 44.1%). Artificially increased levels ofbioturbation reduced by half the MeHg concentrationsand % of added total Hg in sediment and water. In allsystems, 55–68% of total Hg and MeHg in water wereassociated to suspended particles >1m. MeHgbioaccumulation factors (BFs) from water ranged270–8100 and from sediment, 0.2–5.7 (wet weight basis). BFs in relation to water where 3 times higher for MeHg than for total Hg.Item Methylmercury Production and Distribution in Aquatic Systems(Elsevier, 1999) Ikingura, Justinian R.; Akagi, HirokatsuMercury methylation and partitioning between sediment, water and fish were studied in river sediment spiked with mercuric chloride at levels of 1, 5 and 10 ppm as Hg. Maximum methylmercury production in the sediment occurred during the first week of incubation, with concentrations reaching 45.5 ngrg dry wt. . Equilibrium conditions were Ž . established 3]4 weeks after the contamination of the sediment with mercury. Methylmercury partitioning between sediment and water yielded methylmercury levels of 25]154 ngrl in the fish aquariums and 0.26 ngrl in the fish-free control after 1 week of incubation. Equilibrium levels were 1.5]5.5 ngrl and 0.53 ngrl, respectively, during the 7th week. Over 50% of the methylmercury in whole water were in soluble form or associated with colloidal particulate -1 mm. Mercury concentration in fish increased almost exponentially from 30 ppb to an average of 345 ppb within 3 weeks. Mercury uptake rates by fish were in the range of 10]18 ngrg per day during the 2nd and 3rd weeks, high rates occurring in water with methylmercury to total mercury ratios )0.45. The partition coefficients for total mercury and methylmercury between fish and water Ž . K were 5000]7000 and 10 000]22 000, respectively. Large f ] w differences were observed in methylmercury production in sediment]water incubation with fish and the fish-free control. Equilibrium methylmercury concentrations in sediment were in the range 15]32 ngrg in the aquariums containing fish and 3]4.5 ngrg in the fish-free control. The significance of fish in mercury methylation in the aquariums still remains to be clarified as fish itself cannot methylate mercury in vivo.Item Monitoring of Fish and Human Exposure to Mercury Due To Gold Mining in the Lake Victoria Goldfields, Tanzania(Elsevier, 1996) Ikingura, Justinian R.; Akagi, HirokatsuMonitoring of environmental and human exposure to mercury in the Nungwe Bay area of the Lake Victoria goldfields, Tanzania, has revealed low mercury concentrations in fish (range: 1.8-16.9 ppb, mean: 7.0 ppb) and human hair (range: 156-5433 ppb, mean: 947 ppb) that represent background levels. Gold mining has not produced a significant increase in environmental methylmercury that is available for bioaccummulation in aquatic food chains. Urinary mercury levels in gold mine workers frequently exposed to Hg vapour in amalgamation and burning of amalgam were significantly higher (mean: 241 ng/ml) than those in the general mine population not occupational exposed to Hg (mean: 2.6 ng/ml). Rotation of mine duties reduced Hg exposure levels and hence the risk of intoxication in the gold mine workers. The lowest urinary and hair mercury levels were found in the Nungwe Bay fishing village population. This was consistent with the low mercury content of fish consumed by the inhabitants of the Nungwe BayItem Petrology of the Marginal Part of Mbozi Syenite—Gabbro Complex, Mbozi District, Mbeya Region, Tanzania(Elsevier, 1984) Basu, Nitin K.; Ikingura, Justinian R.Petrology of the marginal portion of the Mbozi syenite-gabbro complex occurring in southwestern Tanzania was studied. Petrographically, four rock types are recognised: gabbro, nepheline gabbro, nepheline syenite and nepheline-sodalite syenite. Texturally, the rocks exhibit a typical poikilitic texture in gabbro with large plates of undeformed plagioclase enclosing pyroxene and nepheline crystals to a protoclastic nepheline syenite and nepheline-sodalite syenite in which phenocrysts of nepheline, sodalite and pyroxene are set in a groundmass of shattered feldspars. Pyroxene and amphibole are sodic and aluminous in composition and their paragenesis indicates incomplete reaction relation; amphiboles exhibit exsolution of Ti in the form of ilmenite. It is concluded that an initially undersaturated magma favoured crystallization of nepheline and pyroxene in preference to plagioclase feldspars. Later shearing and granulation of the plagioclase and permiation of alkalic fluids may have given rise to the marginal alkaline rocks. Nepheline and mafic crystals are unaffected by the shearing as the strain was absorbed by the host plagioclase crystals. Twinning in pyroxene and amphibole crystals may, however, indicate effect of strain. Straight line variation diagrams of major elements and some of the trace elements and their ratios indicate probable mixing of magmas to produce the observed variation in rock types.Item Preparation and Characterization of a Soil Reference Material from a Mercury Contaminated Site for Comparability Studies(2006) Kocman, David; Bloom, Nicolas S.; Akagi, Hirokatsu; Telmer, Kevin; Hylander, Lars; Fajon, Vesna; Jereb, Vesna; Jaćimović, Radojko; Smodiš, B.; Ikingura, Justinian R.; Horvat, MilenaThe preparation and characterization of a soil reference material (SOIL-1) from a site polluted with mercury due to the past mercury mining in Idrija, Slovenia is reported. Homogeneity tests and intercomparison exercises for total (T-Hg) and methylmercury (MeHg) were performed. In addition, selective sequential extraction was applied for Hg fractionation, and multielemental analyses were performed by k(0) standardization neutron activation analysis (k(0)-INAA) and inductively coupled mass spectrometry (ICP-MS) for other trace elements. Comparison of different analytical methods, as well as the distribution of data were critically evaluated using descriptive statistics and analysis of variance (ANOVA). Due to the nugget effect (cinnabar particles representing more than 90% of the mercury), homogeneity for T-Hg determination was difficult to achieve. The intercomparison exercise indicated that in order to obtain comparable results for total mercury (T-Hg) sample decomposition by HF must be performed. These data are then in good agreement with non-destructive methods such as k(0)-INAA. Accepted reference values calculated taking into account the results obtained by six and three laboratories, respectively, were 67.1+/-11.3 mg kg(-1) for T-Hg and 4.0+/-1.3 ng g(-1) for MeHg (95% confidence intervals). However, the results obtained for Hg fractionation displayed significant differences in the organically bound fraction and elemental Hg. Results obtained by two laboratories using totally different analytical protocols for other elements showed excellent agreement for most elements. In summary, the results obtained for the SOIL-1 sample were of sufficient quality to suggest its use for quality control in laboratories dealing with mercury contaminated soils.Item Total Mercury and Methylmercury Levels in Fish from Hydroelectric Reservoirs in Tanzania(Elsevier, 2003) Ikingura, Justinian R.; Akagi, HirokatsuTotal mercury (THg) and methylmercury (MeHg) levels have been determined in fish species representing various tropic levels in four major hydroelectric reservoirs (Mtera, Kidatu, Hale-Pangani, Nyumba ya Mungu) located in two distinct geographical areas in Tanzania. The Mtera and Kidatu reservoirs are located along the Great Ruaha River drainage basin in the southern central part of the country while the other reservoirs are located within the Pangani River basin in the north eastern part of Tanzania. Fish mercury levels ranged from 5 to 143 μg/kg (mean 40 μg/kg wet weight) in the Mtera Reservoir, and from 7 to 119 μg/kg (mean 21 μg/kg) in the Kidatu Reservoir downstream of the Great Ruaha River. The lowest THg levels, in the range 1–10 μg/kg (mean 5 μg/kg), were found in fish from the Nyumba ya Mungu (NyM) Reservoir, which is one of the oldest reservoirs in the country. Fish mercury levels in the Pangani and Hale mini-reservoirs, downstream of the NyM Reservoir, were in the order of 3–263 μg/kg, with an average level of 21 μg/kg. These THg levels are among the lowest to be reported in freshwater fish from hydroelectric reservoirs. Approximately 56–100% of the total mercury in the fish was methylmercury. Herbivorous fish species contained lower THg levels than the piscivorous species; this was consistent with similar findings in other fish studies. In general the fish from the Tanzanian reservoirs contained very low mercury concentrations, and differed markedly from fish in hydroelectric reservoirs of similar age in temperate and other regions, which are reported to contain elevated mercury concentrations. The low levels of mercury in the fish correlated with low background concentrations of THg in sediment and flooded soil (mean 2–8 μg/kg dry weight) in the reservoir surroundings. This suggested a relatively clean reservoir environment that has not been significantly impacted by mercury contamination from natural or anthropogenic sources.Item Trace Element Geochemistry and Petrogenesis of the Granitoids and High-K Andesite Hosting Gold Mineralisation in the Archean Musoma-Mara Greenstone Belt, Tanzania(Elsevier, 2014) Kazimoto, Emmanuel O.; Ikingura, Justinian R.Modern and ancient active continental margins are well known for their potential for hosting important gold deposits. The Neoarchean Musoma-Mara Greenstone Belt of the Tanzania Craton is also known for hosting several important gold deposits. Previous geochemical studies of the belt demonstrated that the rocks formed along Neoarchean convergent margins. The host rocks of the three important deposits in this belt had not yet been geochemically investigated. Therefore, we studied the host rocks of the Gokona, Nyabigena and Nyabirama gold deposits in the Neoarchean Musoma-Mara Greenstone Belt of the Tanzania Craton to determine the tectonic setting of their formation and constrain their petrogenesis. The host rocks of the Gokona and Nyabigena deposits are classified as high-K andesite, whereas the host rocks of the Nyabirama deposit are classified primarily as trondhjemite and granite and minor granodiorite (TGG). The high-K andesite and TGG were formed in an active continental margin similar to that of other Neoarchean volcanic rocks found in the Musoma-Mara Greenstone Belt. The host rocks contain low Ni and Cr concentrations and are characterised by negative Eu anomalies (Eu/Eu* = 0.67-0.72 and 0.17-0.6). The chondrite-normalised rare earth element (REE) patterns of the rocks display strong enrichment in light REEs over heavy REEs (high-K andesite (La/Yb)N = 21.7-35.6, and TGG (La/Yb)N = 2.4-94.4). Moreover, the primitive normalised diagrams show enrichment in large-ion lithophile elements (Ba, Rb, Th and K), negative Nb and Ta anomalies and depletion in heavy rare earth elements and high field-strength elements (Y and Ti). The high-K andesite has a Nb/Ta value close to that of depleted mantle (mean = 15.0), lower Zr/Sm values (19.4-30.6) and higher concentrations of REEs, large ion lithophile elements, Sr (607 ppm) and Y than in the TGG. The TGG has a low mean Nb/Ta value (13.2) and Sr concentration (283 ppm) and a lower amount of HREEs and higher values of Zr/Sm (32.5-91.0) compared to the high-K andesite. However, all of the rock types contain high Ta/Yb and Th/Yb values (high-K andesite and granitoids; mean = 5.9 and 0.8, 17 and 21.3). These characteristics are interpreted as an indication of the formation of the Gokona, Nyabigena and Nyabirama host rocks from the hydrous partial melting of mantle peridotite, similar to the evolution of classical island arc rocks. The primary melts subsequently underwent fractional crystallisation to form high-K andesite, dacite and TGG prior to their extrusion or emplacement in the continental crust.