Browsing by Author "Chibura, Patrick E."
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Item Occurrence of organochlorine and organophosphorus pesticide residues in poultry feeds, raw and cooked eggs from selected farms in Ilala and Kibaha Districts, Tanzania(University of Port Harcourt, 2018) Mahugija, John A.M.; Chibura, Patrick E.; Lugwisha, Esther H.J.This study assessed the levels of seventeen pesticides and metabolites residues in chicken feeds and raw eggs as well as the effects of processing methods on the levels in eggs in samples obtained from six poultry farms in Ilala and Kibaha districts, Tanzania. Extraction was performed by solid dispersion method and the extracts were cleaned-up by adsorption column chromatography. The analytes were determined by Gas Chromatography–Mass Spectrometry (GC–MS). The highest mean concentrations of the contaminants in feeds and eggs were as follows, respectively: aldrin 0.62 and 2 mg/kg, dieldrin 0.71 and 1.3 mg/kg, total DDT 6.68 and 8.14 mg/kg, total endosulfan 3.53 and 3.74 mg/kg, total HCHs 0.91 and 1.21 mg/kg, chlorpyrifos 12.2 and 0.59 mg/kg, fenitrothion 4.9 and 0.64 mg/kg and pirimiphos methyl 22.11 and 1.6 mg/kg. Chicken feeds were found to be the most contaminated followed by raw eggs and finally cooked eggs. Most of the concentrations were above the maximum residue limits (MRLs) indicating risks and concerns. Proper selection and preparation of poultry feeds could reduce the levels in the feeds and eggs.Item Residues of pesticides and metabolites in chicken kidney, liver and muscle samples from poultry farms in Dar es Salaam and Pwani, Tanzania(Elsevier Ltd., 2018) Mahugija, John A.M.; Chibura, Patrick E.; Lugwisha, Esther H.J.The concentrations of organochlorine and organophosphorus pesticides and metabolites were investigated in chicken kidney, liver and muscle samples obtained from chickens collected from four poultry farms in Dar es Salaam and Pwani regions in Tanzania. The samples were extracted by solid dispersion using cyclohexane:ethyl acetate. The extracts were cleaned by adsorption column chromatography. The analytes were determined using gas chromatography-mass spectrometry (GC-MS). The concentrations of total DDT, total endosulfan and total HCHs in the samples ranged from 0.71 to 26, 0.3 to 7.9 and 0.02-10.4 mg/kg lipid weight (lw), respectively. The highest concentrations of aldrin, dieldrin, chlorpyrifos, fenitrothion and pirimiphos methyl were 5.5, 4.8, 9.7, 5.6 and 7.8 mg/kg lw, respectively. The highest concentrations of the contaminants were found in the kidney and liver samples. The sites in Dar es Salaam showed the highest concentrations of the compounds. Most of the concentrations were above the maximum residue limits (MRLs) indicating risks and concerns for livestock and public health.