Ibahati, Sempeho S.Kim, Hee T.Mubofu, Egid B.Hilonga, Askwar2016-06-152016-06-152014-08Sempeho, S.I., Kim, H.T., Mubofu, E. and Hilonga, A., 2014. Meticulous overview on the controlled release fertilizers. Advances in Chemistry, 2014.http://hdl.handle.net/20.500.11810/2508Owing to the high demand for fertilizer formulations that will exhaust the possibilities of nutrient use efficiency (NUE), regulate fertilizer consumption, and lessen agrophysicochemical properties and environmental adverse effects instigated by conventional nutrient supply to crops, this review recapitulates controlled release fertilizers (CRFs) as a cutting-edge and safe way to supply crops’ nutrients over the conventional ways. Essentially, CRFs entail fertilizer particles intercalated within excipients aiming at reducing the frequency of fertilizer application thereby abating potential adverse effects linked with conventional fertilizer use. Application of nanotechnology and materials engineering in agriculture particularly in the design of CRFs, the distinctions and classification of CRFs, and the economical, agronomical, and environmental aspects of CRFs has been revised putting into account the development and synthesis of CRFs, laboratory CRFs syntheses and testing, and both linear and sigmoid release features of CRF formulations. Methodical account on the mechanism of nutrient release centring on the empirical and mechanistic approaches of predicting nutrient release is given in view of selected mathematical models. Compositions and laboratory preparations of CRFs basing on in situ and graft polymerization are provided alongside the physical methods used in CRFs encapsulation, with an emphasis on the natural polymers, modified clays, and superabsorbent nanocomposite excipients.enJournal Article, Peer Reviewed10.1155/2014/363071